Product ID:MIL-C-46168D, PART B 4:1 BLEND
MSDS Date:01/01/1988
FSC:8010
NIIN:01-141-2415
Kit Part:Y
MSDS Number: BHNFG

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

OSHA PEL NE

ACGIH TLV: NE

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.7%

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY LEAD TO BRONCHITIS,
BRONCHIAL SPASM & PULMONARY EDEMA. CHEMICAL OR HYPERSENSITIVE
PNEUMONITIS WITH FLU LIKE SYMPTOMS, VOMITING MAY CAUSE ASPIRATIONOF
THE SOLVENT RESULTING IN CHEMICAL PNE UMONITIS. CONTACT WITH BUTYL
ACETATE ORXYLENE CAN RESULT IN DRY, DEFATTED & CRACKED SKIN CAUSING
POSSIBLE INFECTIONS.
Explanation of Carcinogenicity:NONE KNOWN.
Effects of Overexposure:EYES: IRRI, TEARING, REDNESS & SWELLING ALONG
WITH STINGING & DUST SENSATION. SKIN: REDDENING, SWELLING, RASH,
SCALING OR BLISTERING AND DERMATITIS. INHAL: IRRIT. THE
MUCOUS MEMBRANES IN NO SE,THROAT,LUNGS,COUGHING,CHST
DISCOMFORTINGSTION: IRRI & CORROSIVE ACTION TO MOUTH, STOMACH
TISSUE & DIGESTIVE TRACK.
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA & HYPERRACTIVITY, SKIN ALLERGIES, AND
ECZMA.

First Aid:EYE: FLUSH W/CLN LKWRM WTR,LW PRESS FOR 15 MINS,LIFTING
EYELIDS, GET MED ATTN SKIN: WASH AREA W/SOAP & WTR. REMOVE
CONTAM. CLOTHING IMMED., GET MEDCL ATTN INGST: DONOT INDUCE
VOMITING. DONOT GIVE ANYTHING BY MOUTH, CONSULT A PHYSICIANINHAL:
REMOVE TO FRESH AIR,GIVE ARTIFICIAL RESP. AS NEEDED, GET MEDICAL
ATTN ASTHMATIC TYPE SYMPTOMS MAY DEVELOP & MAY BE IMMED. OR
DELAYED UP TO SEVERAL HRS

Flash Point Method:PMCC
Flash Point:91F/33C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING. ISOLATE
FROM HEAT, ELEC. EQUIP, SPARKS ANDOPEN FLAME. CLOSED CONTAINER MAY
EXPLODE EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:BURST WHEN CONTAMINATED WITH WATER
CREATING CO2, STAGNANT AIR MAY CAUSE VAPORS TO BUILD UP & TRAVEL
ALONG GROUND TO IGNITION SOURCE WHICH MAY CAUSE FLASH BACK.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION & VENT AREA.
DIKE OR IMPOUND SPILLED MATERIAL, AVOID MORE SPILLAGE IF POSS.
COLLECT MATL IN OPEN CONTNR TO SAFE PLACECOVER LOOSELY & ALLOW TO
STAND FOR 24-48 HRS. WASH DOWN SPILL AREAS WITH DECONTAMINATION
SOLUTIONS.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARK & OPEN
FLAME. STORE IN TIGHTLY CLOSED CONTAINER TO PREVENT MOISTURE
CONT-AMINATION. IDEAL STORAGE 50-81 F/ 10-27 C.
Other Precautions:DO NOT RESEAL IF CONTAMINATION IS SUSPECTED. IF
CONTAINER IS EXPOSED TO HIGH HEAT. IT CAN BE PRESSURIZED &
POSSIBLE RUPTURE EXPLOSIVELY. THIS GAS CAN CAUSE SEALED CONTAINERS
TO EXPAND AND POSSIBLY RUPTURE EXPLOSIVELY.

Respiratory Protection:POSITIVE PRESSURE SUPPLIED AIR RESPIRATOR IS
MANDATORY FOR CONFINED AREAS OTHER APPROVED PROTECTION, AIR
PURIFYING OR FRESH AIR SUPPLIED RESPIRATORS.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATION OF THE SOLVENT,HDI, & POLYISOCYANATE BELOW THEIR
TLV'S
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES,SPLASH GOGGLES,FACESHIELD
Other Protective Equipment:SAFETY SHOWERS & EYEWASH STATIONS SHOULD BE
AVAILABLE AND SHOULD BE USED WHEN NEEDED.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING & BEFORE
USING RESTROOMSSMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
KEY1:F4. KIT CONSISTS OF TWO PARTS. PART ONE HAS PNI A, PART TWO HAS
PNI B, SAME NSN.

HCC:F3
Boiling Pt:B.P. Text:NE
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:30 CA

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES AND/OR SHOCK
FROM DROPPING.
Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CARBON DIOXIDE,
CARBON MONOXIDE, OXIDESOF NITROGEN, AND TRACES OF HNC AND HDI.
Conditions to Avoid Polymerization:IF IN CONTACT WITH MOISTURE OR OTHER
MATERIAL WHICH REACTS WITH ISOCYANATES. MAY OCCUR AT TEMPERATURE
>400 F/ 204 C.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL REGULATIONS. INCINERATION IS PREFERRED. EMPTY CON-TAINER MUST
BE HANDLED W/CARE DUE TO PROD. RESIDUE& FLAMMABLE VAPOR. DO NOT
HEAT OR CUT ON OR NEAR EMPTY CONTAINERS WITH ELECTRIC OR GAS
TOURCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.